WAMP second virtual host not working/re-directing to first - wordpress

Question

I got VH working fine.
Localhost and my first site (which is attached to a domain) work absolutely fine, no issues.
However I wanted to add a second site (3rd if you include localhost) to experiment with a new site. However after having added it, it simply seems to re-direct to the first site's domain. They are both wordpress installations (although the 3rd isnt installed yet as I cant access it) but I'm not sure if that's relevant.
Here's my two relevant files;
httpd-vhosts.conf
<VirtualHost *:80>
DocumentRoot "c:/wamp/www"
ServerName localhost
ServerAlias localhost
<Directory "c:/wamp/www">
AllowOverride All
Require local
</Directory>
</VirtualHost>
<VirtualHost *:80>
DocumentRoot "c:/wamp/www/mysite"
ServerName mysite.local
<Directory "c:/wamp/www/mysite">
AllowOverride All
Require local
</Directory>
ErrorLog "logs/mysite-error.log"
CustomLog "logs/mysite-access.log" common
</VirtualHost>
<VirtualHost *:80>
ServerAdmin info#mydomain.co.uk
DocumentRoot "c:/wamp/www/wordpress"
ServerName mydomain.co.uk
ServerAlias www.mydomain.co.uk
<Directory "c:/wamp/www/wordpress">
AllowOverride All
</Directory>
ErrorLog "logs/wordpress-error.log"
CustomLog "logs/wordpress-access.log" common
</VirtualHost>
As explained.. localhost works, mydomain.co.uk works (name changed for privacy reasons but it works!). mysite.local does not it just redirects to mydomain.co.uk ???? (I tried a bunch of names including mysite.localhost, etc etc-- nothing works! I don't care what the name is I just want to be able to access it, will be buying a domain for it soon).
Any help is appreciated. Thank-you!
Here's hosts file although it's pretty self explanatory;
127.0.0.1 localhost
127.0.0.1 mysite.locals
127.0.0.1 mydomain.co.uk
::1 localhost
::1 mysite.local
::1 mydomain.co.uk